Fundamentals of Engineering Thermodynamics 8th Edition

Published by Wiley
ISBN 10: 1118412931
ISBN 13: 978-1-11841-293-0

Chapter 12 - Problems: Developing Engineering Skills - Page 791: 12.6

Answer

(a) $53.33\frac{lb}{lb/space mole}$ (b) $0.4548$, $0.5452$

Work Step by Step

(a) We can find the required molecular weight as follows: $n=\frac{PV}{RT}$ $\implies n=\frac{40\times 45 \times 144}{1545.35(150+459.67)}$ This simplifies to: $n=0.275lb\space mole$ Now $M=\frac{m}{n-\frac{m_{O_2}}{M_{O_2}}}$ We plug in the known values to obtain: $M=\frac{8}{0.275-\frac{4}{32}}$ This simplifies to: $M=53.33 \space \frac{lb}{lb\space mole}$ (b) The required mole fraction can be determined as follows: First for oxygen $y_{O_2}=\frac{\frac{4}{12}}{\frac{32}{0.0229}}$ This simplifies to: $y_{O_2}=0.4548$ Now, for unknown gas $y=\frac{{8}{12}}{\frac{53.33}{0.0229}}$ This simplifies to: $y=0.5452$
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