Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 3 - The Structure of Crystalline Solids - Questions and Problems - Page 102: 3.67

Answer

45.88°

Work Step by Step

Required: Determine the expected diffraction angle for the first-order reflection from the (310) set of planes for BCC chromium (Cr) when monochromatic radiation of wavelength 0.0711 nm is used. Solution: From Table 3.1, atomic radius of Chromium is 0.1249 nm. Calculating for the value of lattice parameter $a$, $a = \frac{4R}{\sqrt 3} = \frac{(4)(0.1249)}{\sqrt 3} = 0.2884 nm$ Using Equation 3.22, $d_{310}$ is computed as, $d_{310} = \frac{a}{\sqrt (3)^{2} + (1)^{2} + (0)^{2}} = \frac{0.2884 nm}{\sqrt 10} =0.0912 nm $ Modifying Equation 3.21 to compute the value of θ, $sin θ = \frac{nλ}{2d_{310}} = \frac{(1)(0.0711 nm)}{(2)(0.0912 nm)} = 0.3898$ $θ = sin^{-1}(0.3898) = 22.94°$ Thus, $2θ = (2)(22.94°) = 45.88°$
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