Lehninger Principles of Biochemistry 6th Edition

Published by W.H. Freeman
ISBN 10: 1-42923-414-8
ISBN 13: 978-1-42923-414-6

Chapter 7 - Carbohydrates and Glycobiology - Problems - Page 278: 1

Answer

D and L designation applies only for chiral molecules. When glyceraldehyde is reduced to glycerol, there are no chiral carbons in the molecule, so D and L isomer designation is not applicable.

Work Step by Step

When glyceraldehyde is reduced to glycerol, C1 and C3 have the same atoms and stereochemistry, so C2 is not chiral anymore. This means D and L designation is not applicable to glycerol.
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