Answer
See explanation
Work Step by Step
$KBr \Rightarrow K^+ + Br^-$
Water, a polar substance, effectively pulls apart the ionic compound $KBr$ to separate into its ions, $K^+$ and $Br^-$. In this case, the H atoms would align with $Br^-$ and the Oxygen would align with $K^+$.
Because $C_2H_5OH$ is a covalent compound and does not break up into ions in water, the covalent compound does not split. Instead, water aligns such that H atoms attract toward the partially negative end of $C_2H_5OH$ while the O atoms attract toward the partially positive end of $C_2H_5OH$