Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition)

Published by Prentice Hall
ISBN 10: 0321908449
ISBN 13: 978-0-32190-844-5

Chapter 10 - Section 10.5 - The pH Scale - Questions and Problems - Page 344: 10.40d

Answer

The pH of that solution is equal to 11.92

Work Step by Step

1. Write the $K_w$ expression for the water equilibrium. Then substitute the value for $[OH^-]$, and solve for $[H_3O^+]$: $[OH^-] * [H_3O^+] = Kw = 10^{-14}$ $ 8.0 \times 10^{- 3} * [H_3O^+] = 10^{-14}$ $[H_3O^+] = \frac{10^{-14}}{ 8.0 \times 10^{- 3}}$ $[H_3O^+] = 1.2 \times 10^{- 12}M$ 2. Calculate the pH value $pH = -log[H_3O^+]$ $pH = -log( 1.2 \times 10^{- 12})$ $pH = 11.920819$ 3. Determine the right number of significant figures. The $[H_3O^+]$ had 2 significant figures: $1.2 \times 10^{-12}$. So, there must be only 2 numbers on the right of the decimal point of the pH. - Round the number to 2 decimal places: $pH = 11.92$
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