Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 18 Principles of Chemical Reactivity: Entropy and Free Energy - Study Questions - Page 711d: 47

Answer

See below

Work Step by Step

The reaction is exothermic, so $Δ_{r}$H° should be negative. Also, a gas and an aqueous solution are formed, so $Δ_{r}$S° should be positive. The calculated values are $Δ_{r}$H° = −183.32 kJ/mol-rxn (with a negative sign as expected) and $Δ_{r}$S° = −7.7 J/K ∙ mol-rxn The entropy change is slightly negative, not positive as predicted. The reason for this is the negative entropy change upon dissolving NaOH. The $OH^{-}$ ions in water hydrogen-bond with water molecules, an effect that also leads to a small, negative entropy change.
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