General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 16 - Carboxylic Acids and Esters - Additional Questions and Problems - Page 603: 16.53

Answer

a) Ethanoic acid will have a higher boiling point than 1-propanol. This is because two ethanoic acid hydrogen molecules will bond to form a dimer. This dimer will double the molar mass of the ethanoic acid, which will then require a higher temperature to reach boiling point. b) Ethanoic acid will form hydrogen bonds, while butane will not, because butane only has London Dispersion, meaning it will have a low boiling point.

Work Step by Step

a) Ethanoic acid will have a higher boiling point than 1-propanol. This is because two ethanoic acid hydrogen molecules will bond to form a dimer. This dimer will double the molar mass of the ethanoic acid, which will then require a higher temperature to reach boiling point. b) Ethanoic acid will form hydrogen bonds, while butane will not, because butane only has London Dispersion, meaning it will have a low boiling point.
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.