General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Published by Pearson
ISBN 10: 0321967461
ISBN 13: 978-0-32196-746-6

Chapter 7 - Chemical Reactions and Quantities - 7.7 Mass Calculations for Reactions - Questions and Problems - Page 265: 7.70

Answer

a. $$2H_2S(g) + 3O_2(g) \longrightarrow 2SO_2(g) + 2H_2O(g)$$ b. 3.52 g of $O_2$ c. 51.4 g of $SO_2$ d. 149 g of $O_2$

Work Step by Step

a. 1. Identify each reactant and product, and write the unbalanced reaction. Reactants: Dihydrogen sulfide gas: $H_2S(g)$ Oxygen gas: $O_2(g)$ Products: Sulfur dioxide gas: $SO_2(g)$ Water vapor: $H_2O(g)$ $$H_2S(g) + O_2(g) \longrightarrow SO_2(g) + H_2O(g)$$ 2. Balance the equation. - There are 3 oxygens in the products side, but only 2 on the reactants side. In order to add an extra oxygen atom to the reactants side, we can put $\frac 32$ as the coefficient of $O_2(g)$. $$H_2S(g) + \frac 32O_2(g) \longrightarrow SO_2(g) + H_2O(g)$$ Now, everything is balanced. We only need to remove the fraction, by multiplying all coefficients by 2: $$2H_2S(g) + 3O_2(g) \longrightarrow 2SO_2(g) + 2H_2O(g)$$ For b., c. and d.: - Find the conversion factors and calculate each mass. b. $$ \frac{ 2 \space moles \space H_2S }{ 3 \space moles \space O_2 } \space and \space \frac{ 3 \space moles \space O_2 }{ 2 \space moles \space H_2S }$$ $ H_2S $ : ( 1.008 $\times$ 2 )+ ( 32.06 $\times$ 1 )= 34.08 g/mol $$ \frac{1 \space mole \space H_2S }{ 34.08 \space g \space H_2S } \space and \space \frac{ 34.08 \space g \space H_2S }{1 \space mole \space H_2S }$$ $ O_2 $ : ( 16.00 $\times$ 2 )= 32.00 g/mol $$ \frac{1 \space mole \space O_2 }{ 32.00 \space g \space O_2 } \space and \space \frac{ 32.00 \space g \space O_2 }{1 \space mole \space O_2 }$$ $$ 2.50 \space g \space H_2S \times \frac{1 \space mole \space H_2S }{ 34.08 \space g \space H_2S } \times \frac{ 3 \space moles \space O_2 }{ 2 \space moles \space H_2S } \times \frac{ 32.00 \space g \space O_2 }{1 \space mole \space O_2 } = 3.52 \space g \space O_2 $$ c. $$ \frac{ 3 \space moles \space O_2 }{ 2 \space moles \space SO_2 } \space and \space \frac{ 2 \space moles \space SO_2 }{ 3 \space moles \space O_2 }$$ $ O_2 $ : ( 16.00 $\times$ 2 )= 32.00 g/mol $$ \frac{1 \space mole \space O_2 }{ 32.00 \space g \space O_2 } \space and \space \frac{ 32.00 \space g \space O_2 }{1 \space mole \space O_2 }$$ $ SO_2 $ : ( 16.00 $\times$ 2 )+ ( 32.06 $\times$ 1 )= 64.06 g/mol $$ \frac{1 \space mole \space SO_2 }{ 64.06 \space g \space SO_2 } \space and \space \frac{ 64.06 \space g \space SO_2 }{1 \space mole \space SO_2 }$$ $$ 38.5 \space g \space O_2 \times \frac{1 \space mole \space O_2 }{ 32.00 \space g \space O_2 } \times \frac{ 2 \space moles \space SO_2 }{ 3 \space moles \space O_2 } \times \frac{ 64.06 \space g \space SO_2 }{1 \space mole \space SO_2 } = 51.4 \space g \space SO_2 $$ d. $$ \frac{ 2 \space moles \space H_2O }{ 3 \space moles \space O_2 } \space and \space \frac{ 3 \space moles \space O_2 }{ 2 \space moles \space H_2O }$$ $ H_2O $ : ( 1.008 $\times$ 2 )+ ( 16.00 $\times$ 1 )= 18.02 g/mol $$ \frac{1 \space mole \space H_2O }{ 18.02 \space g \space H_2O } \space and \space \frac{ 18.02 \space g \space H_2O }{1 \space mole \space H_2O }$$ $ O_2 $ : ( 16.00 $\times$ 2 )= 32.00 g/mol $$ \frac{1 \space mole \space O_2 }{ 32.00 \space g \space O_2 } \space and \space \frac{ 32.00 \space g \space O_2 }{1 \space mole \space O_2 }$$ $$ 55.8 \space g \space H_2O \times \frac{1 \space mole \space H_2O }{ 18.02 \space g \space H_2O } \times \frac{ 3 \space moles \space O_2 }{ 2 \space moles \space H_2O } \times \frac{ 32.00 \space g \space O_2 }{1 \space mole \space O_2 } = 149 \space g \space O_2 $$
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