Organic Chemistry (8th Edition)

Published by Pearson
ISBN 10: 0321768418
ISBN 13: 978-0-32176-841-4

Chapter 23 - Carbohydrates and Nucleic Acids - Problems - Page 1106: Problem 23-5

Answer

The answer is shown in the picture.

Work Step by Step

The Cahn Ingold Prelog (CIP) System is used for naming chiral centers, 1. Prioritize the four groups around a chiral center according to atomic number. 2. Orient the chiral centre such that the 4th priority substituent is pointing away from the viewer 3. Trace the path of priorities 1, 2 and 3. - If the path traced from 1-2-3 is clockwise, the chiral center is assigned (R) - If the path traced is counterclockwise, the chiral center is assigned (S) If the 4th substituent is not pointing away from the viewer, and instead is pointing to the viewer: 3. Trace the path of priorities 1, 2 and 3. - If the path traced from 1-2-3 is clockwise, the chiral center is assigned (S) - If the path traced is counterclockwise, the chiral center is assigned (R)
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