Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Chapter 1 - Topic 1A - The perfect gas - Discussion Questions - Page 54: 1A.2

Answer

Partial pressure of a gas in a mixture of gases is the pressure the gas would exert if it were the only component existing at the same volume and temperature. --- Dalton's law is a limiting law because it applies only under the conditions where the gases do not effect each other. This will be true only in the limit of zero pressure where the molecules of the gases are very distant from each other. Hence we can imply that Dalton's law applies only for a mixture of ideal gases. Dalton's law is represented as the sum of the partial pressures of the individual gases in the mixture. Ptotal $=\mathrm{p}_{\mathrm{a}}+\mathrm{p}_{\mathrm{b}}+\mathrm{p}_{\mathrm{c}}$ Where $\mathrm{a}, \mathrm{b}$ and $\mathrm{c}$ represent the individual gases. This expression emerges from the fact that in an ideal gas the molecules are so distant from each other that they do not interact with each other.

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