Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Chapter 6 - Topic 6A - The equilibrium constant - Exercises - Page 272: 6A.1(b)

Answer

a) The gibbs free energy of te reaction is: $-0.64 \space kj$ and b) The gibbs free energy of te reaction is: $-0.123 \space kj$

Work Step by Step

Let us consider a reaction $A \to 2B$ Case I: We are given that the extent for a reaction $\triangle \xi = 0.10 mol$ Now, $\triangle_r G =(\dfrac{\partial G}{\partial \xi})_{p, T}$ Plug in the data . $\partial G=\triangle_r G \cdot \partial \xi=-6.4 \space kj/ mol \times 0.60 space mol=-0.64 kJ$ Case 2: Let us consider a reaction $2A \to B$ We are given that the extent for a reaction $\triangle \xi = 0.051 mol$ Now, $\triangle_r G =(\dfrac{\partial G}{\partial \xi})_{p, T}$ Plug in the data . $\partial G=\triangle_r G \cdot \partial \xi=-2.41 \space kj/ mol \times 0.051 \space mol=-0.123 kJ$ Therefore, a) The gibbs free energy of the reaction is: $-0.64 \space kj$ and b) The gibbs free energy of the reaction is: $-0.123 \space kj$ .
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