Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Chapter 7 - Topic 7A - The origins of quantum mechanics - Exercises - Page 310: 7A.3(b)

Answer

$(a) \space v = 17.3 \space km/s$ $(b) \space v = 631 \space km/s$ $(c) \space v = 77.4 \space km/s$

Work Step by Step

The incident energy of the photon would get converted into Kinetic Energy. $\therefore E_{photon} = \frac{1}{2}mv^2$ where m is mass of Helium atom($^4He$). Hence, $v = \sqrt{\frac{2E_{photon}}{m}}$ $m = 4.0026m_u =4\times 1.66 \times 10^{-27} = 6.6465 \times 10^{-27} kg$ $a) \space E_{photon} = 9.939\times 10^{-19}J$ $v = \sqrt{\frac{2\times 9.939\times 10^{-19}}{6.6465\times 10^{-27}}} = 17.3 \space km/s$ $b) \space E_{photon} = 1.325\times 10^{-15}J$ $v = \sqrt{\frac{2\times 1.325\times 10^{-15}}{6.6465\times 10^{-27}}} = 631 \space km/s$ $c) \space E_{photon} = 1.99\times 10^{-23}J$ $v = \sqrt{\frac{2\times 1.99\times 10^{-23}}{6.6465\times 10^{-27}}} = 77.4 \space km/s$
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