Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 15 - Chemical Reactions - Problems - Page 801: 15-112

Answer

$ w=C T_{a f}\left(1-\frac{\sqrt{T_0}}{\sqrt{T_{\text {af }}}}\right)^2 $

Work Step by Step

$$ \dot{Q}=\dot{m}\left(h_e-h_i\right)=\dot{m} C\left(T_p-T_u\right) $$ where $\dot{Q}$ is the negative of the heat supplied to the heat engine. That is, $$ \dot{Q}_H=-\dot{Q}=\dot{m} C\left(T_a-T_p\right) $$ Then the work output of the Carnot heat engine can be expressed as $$ \dot{W}=\dot{Q}_H\left(1-\frac{T_0}{T_F}\right)=\dot{m} C\left(T_{a f}-T_p\right)\left(1-\frac{T_0}{T_p}\right). $$ Taking the partial derivative of $\mathrm{W}$ with respect to $T_p$ while holding $T_{\mathrm{af}}$ and $T_{\mathrm{o}}$ constant gives $$ \frac{\partial W}{\partial T_p}=0 \longrightarrow-\dot{m} \mathrm{C}\left(1-\frac{T_0}{T_p}\right)+\dot{m} C\left(T_p-T_{\mathrm{af}}\right) \frac{T_0}{T_p^2}=0 $$ Solving for $T_p$ we obtain $$ T_p=\sqrt{T_0 T_{\mathrm{af}}} $$ which the temperature at which the work output of the Carnot engine will be a maximum. The maximum work output is determined by substituting the relation above into Eq. (1), $$ \dot{W}=\dot{m} C(T_{\text {af }}-T_p)\left(1-\frac{T_0}{T_p}\right)=\dot{m} C\left(T_{\text {af }}-\sqrt{T_0 T_{a f}}\right)\left(1-\frac{T_0}{\sqrt{T_0 T_{\text {af }}}}\right). $$ It simplifies to $$ \dot{W}=\dot{m} C T_{\text {af }}\left(1-\frac{\sqrt{T_0}}{\sqrt{T_{\text {af }}}}\right)^2 $$ or $$ w=C T_{a f}\left(1-\frac{\sqrt{T_0}}{\sqrt{T_{\text {af }}}}\right)^2 $$ This is the desired relation.
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