Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 16 - Chemical and Phase Equilibrium - Problems - Page 829: 16-4C

Answer

See explanation

Work Step by Step

The equilibrium constant for the reaction $\mathrm{CO}+\frac{1}{2} \mathrm{O}_2 \Leftrightarrow \mathrm{CO}_2$ can be expressed as $$ K_p=\frac{N_{\mathrm{CO}_2}^{v_{\mathrm{O}_2}}}{N_{\mathrm{CO}}^{v_{\infty}} N_{\mathrm{O}_2}^{v_{\mathrm{O}_2}}}\left(\frac{P}{N_{\text {total }}}\right)^{\left(v_{\mathrm{CO}_2}-v_{\infty \mathrm{O}}-v_{\mathrm{O}_2}\right)} $$ Adding more $\mathrm{N}_2$ (an inert gas) at constant temperature and pressure will increase $N_{\text {total }}$ but will have no direct effect on other terms. Then to keep the equation balanced, the number of moles of the products $\left(\mathrm{CO}_2\right)$ must increase, and the number of moles of the reactants $\left(\mathrm{CO}, \mathrm{O}_2\right)$ must decrease.
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