Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 16 - Chemical and Phase Equilibrium - Problems - Page 830: 16-7C

Answer

(a) $Kp1$ (b) $1/Kp1$ (c) $Kp1^2$ (d) $Kp1$ (e) $1/Kp1^3$

Work Step by Step

(a) Given the reaction $$H_2\Longleftrightarrow 2H\text{ at }2\text{ atm}$$ The equilibrium constant of the reaction at $3000\text{ K}$ in terms of $K_p$ is $Kp1$. (b) Given the reaction $$2H\Longleftrightarrow H_2\text{ at }1\text{ atm}$$ The equilibrium constant of the reaction at $3000\text{ K}$ in terms of $K_p$ is $1/Kp1$. (c) Given the reaction $$2H_2\Longleftrightarrow 4H\text{ at }1\text{ atm}$$ The equilibrium constant of the reaction at $3000\text{ K}$ in terms of $K_p$ is $Kp1^2$. (d) Given the reaction $$H_2+2N_2\Longleftrightarrow 2H+2N_2\text{ at }2\text{ atm}$$ The equilibrium constant of the reaction at $3000\text{ K}$ in terms of $K_p$ is $Kp1$. (e) Given the reaction $$6H\Longleftrightarrow 3H_2\text{ at }4\text{ atm}$$ The equilibrium constant of the reaction at $3000\text{ K}$ in terms of $K_p$ is $1/Kp1^3$.
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