Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 16 - Chemical and Phase Equilibrium - Problems - Page 831: 16-40

Answer

$\alpha=\sqrt{\frac{K_P}{4+K_P}}$

Work Step by Step

It is to be shown that as long as the extent of the reaction, $\alpha$, for the disassociation reaction $\mathrm{X}_2 \Leftrightarrow 2 \mathrm{X}$ is smaller than one, $\alpha$ is given by $\alpha=\sqrt{\frac{K_P}{4+K_P}}$ The stoichiometric and actual reactions can be written as Stoichiometric: $\mathrm{X}_2 \Leftrightarrow 2 \mathrm{X}$ (thus $v_{\mathrm{X} 2}=1$ and $v_{\mathrm{X}}=2$ ) Actual: $$ \mathrm{X}_2 \Leftrightarrow \underbrace{(1-\alpha) \mathrm{X}_2}_{\text {react. }}+\underbrace{2 \alpha X}_{\text {prod. }} $$ The equilibrium constant $K_p$ is given by $$ K_p=\frac{N_{\mathrm{X}}^{v_{\mathrm{X}}}}{N_{\mathrm{X} 2}^{v_{\mathrm{X} 2}}}\left(\frac{P}{N_{\text {total }}}\right)^{v_{\mathrm{X}}-v_{\mathrm{X} 2}}=\frac{(2 \alpha)^2}{(1-\alpha)}\left(\frac{1}{\alpha+1}\right)^{2-1}=\frac{4 \alpha^2}{(1-\alpha)(1+\alpha)} $$ Solving this expression for $\alpha$ gives $$ \alpha=\sqrt{\frac{K_P}{4+K_P}} $$
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