Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 16 - Chemical and Phase Equilibrium - Problems - Page 836: 16-117

Answer

$\text { (a) } 2.3 \times 10^{-4}$

Work Step by Step

Recall Henry’s law: $$x_{CO_2}=\frac{p_{CO_2}}{H}.$$ Given $H =12.8\text{ MPa}=12.8\times 10^6\text{ Pa}$, total air pressure $100\text{ kPa}=0.1\text{ MPa}$ and the $CO_2$ mole fraction in air $3\%=0.03$, we have: $$p_{CO_2}=0.03\times 0.1\text{ MPa}=0.003\text{ MPa}.$$ Apply Henry's law: $$x_{CO_2}=\frac{0.003}{12.8}\approx 2.3\times 10^{-4}.$$ The correct answer is (a).
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