Materials Science and Engineering: An Introduction

Published by Wiley
ISBN 10: 1118324579
ISBN 13: 978-1-11832-457-8

Chapter 4 - Imperfections in Solids - Questions and Problems - Page 136: 4.18

Answer

$C_{Ag}$ = 44.80% $C_{Au}$ = 46.14% $C_{Cu}$ = 9.06%

Work Step by Step

Given: 44.5 lbm Ag 83.7 lbm Au 5.3 lbm Cu Required: atom percent Solution: $A_{Ag}$ = 107.87 g/mol $A_{Au}$ = 196.97 g/mol $A_{Cu}$ = 63.55 g/mol For easier computation, convert the given weights in grams: $m_{Ag} = (44.5 lbm)(453.6 g/lbm) $= 20,185.2 g $m_{Au} = (83.7 lbm)(453.6 g/lbm) $= 37,966.32 g $m_{Cu} = (5.3 lbm)(453.6 g/lbm) $= 2,404.08 g Using Equation 4.4: $n_{m_{Ag}} = \frac{m_{Ag}}{A_{Ag}} = \frac{20,185.2 g}{107.87 g/mol} = 187.13 mol$ $n_{m_{Au}} = \frac{m_{Au}}{A_{Au}} = \frac{37,966.32 g}{196.97 g/mol} = 192.75 mol$ $n_{m_{Cu}} = \frac{m_{Cu}}{A_{Cu}} = \frac{2,404.08 g}{63.55 g/mol} = 37.83 mol$ Using a modified form of Equation 4.5: $C_{Ag}=\frac{n_{m_{Ag}}} {{{n_{m_{Ag}}}+n_{m_{Au}}}+n_{m_{Cu}}} \times 100 = \frac{187.13}{187.13+192.75+37.83}$ = 44.80% $C_{Au}=\frac{n_{m_{Au}}} {{{n_{m_{Ag}}}+n_{m_{Au}}}+n_{m_{Cu}}} \times 100 = \frac{192.75}{187.13+192.75+37.83}$ = 46.14% $C_{Cu}=\frac{n_{m_{Cu}}} {{{n_{m_{Ag}}}+n_{m_{Au}}}+n_{m_{Cu}}} \times 100 = \frac{37.83}{187.13+192.75+37.83}$ = 9.06%
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