Answer
All vectors in the form of \begin{bmatrix}
x \\
-3x \\
\end{bmatrix} $x \in \mathbb{R}$
Work Step by Step
We know that two vectors are orthogonal if their dot product is $0$.
Hence: $u\cdot v=0\\x\cdot3+y\cdot1=0\\3x+y=0\\y=-3x$
So all vectors in the form of \begin{bmatrix}
x \\
-3x \\
\end{bmatrix} where $x \in \mathbb{R}$ will be orthogonal to $u$