Fundamentals of Biochemistry: Life at the Molecular Level 5th Edition

Published by Wiley
ISBN 10: 1118918401
ISBN 13: 978-1-11891-840-1

Chapter 2 - Water - Exercises - Page 40: 6

Answer

a) $H_{3}C-(CH_{2})_{11}-COO^{-}$ has a polar head ($COO^{-}$) and a singular non-polar tail ($H_{3}C-(CH_{2})_{11}$)., similar to the palmitic acid that composes the micelles. Thus, this molecule would align itself inside the micelle where the polar head is facing the water and the hydrophobic tail is facing the inside of the micelle b) $H_{3}C-(CH_{2})_{11}-CH_{3}$ does not have a polar end. Since it is fully non-polar, it would be completely inside the hydrophobic core of the palmitic acid micelle.

Work Step by Step

Palmitic acid is a saturated fatty acid, its chemical formula is $H_{3}C-(CH_{2})_{14}-COOH$ . Fatty acids are amphipathic molecules, having both polar (COOH head) and non-polar (hydrocarbon chain) components. A micelle is a lipid molecule in aqueous solution, which has arranged itself in a spherical form in response to the polarity of the solution. a) Water is a polar solvent. Polar ends of the fatty acids would align, so that they face the water on the periphery of the micelle. However, the nonpolar fatty acid chains would be present inside the micelle. $H_{3}C-(CH_{2})_{11}-COO^{-}$ would align itself inside the micelle, where its polar end ($COO^{-}$) would be facing the water along with the polar head of the palmitic acid micelle. The saturated fatty acid chain would be present inside the micelle unexposed to polar solvent. b) $H_{3}C-(CH_{2})_{11}-CH_{3}$ does not have any polar end. This is completely saturated and is hydrophobic with no polar group. This would be present completely inside the micelle. This would not at all interact with water. A micelle is having a hydrophobic core, thus due to a hydrophobic moiety of the given molecule, it would be present inside the micelle.
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.