Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 12 - Gases and the Kinetic-Molecular Theory - Exercises - Stoichiometry in Reactions Involving Gases - Page 443: 75

Answer

$V(CH_{4})=415.8l$

Work Step by Step

$T=300K$ $p=825torr=825\times 133.3Pa=109972.5Pa=109.9725kPa$ $m(C_{6}H_{12}O_{6})=1.1kg=1100g$ ---$V(CH_{4})=?$ $n(C_{6}H_{12}O_{6})=\frac{m(C_{6}H_{12}O_{6})}{M(C_{6}H_{12}O_{6})}=\frac{1100g}{180\frac{g}{mol}}=6.11mol$ Bacterial breakdown of a simple sugar can be represented by the following reaction equation: $C_{6}H_{12}O_{6}\rightarrow 3CH_{4}+3CO_{2}$ Since $1mol$ of a simple sugar produces $3mol$ of methane, $n(CH_{4})=3n(C_{6}H_{12}O_{6})=18.33mol$ $pV(CH_{4})=n(CH_{4})RT \implies V(CH_{4})=\frac{n(CH_{4})RT}{p}=\frac{18.33mol\times 8.314\frac{J}{K\times mol}\times 300K}{109.9725kPa}=415.8dm^{3}=415.8l$
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