Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 23 - Organic Chemistry I: Formulas, Names, and Properties - Exercises - Aliphatic Hydrocarbons - Page 945: 20

Answer

a) Alkanes have the general formula $C_{n}H_{2n+2}$ whereas Alkenes have the general formula $C_{n}H_{2n}$ b) Alkenes & Cycloalkanes have the same general formula $C_{n}H_{2n}$. This is because in Cycloalkanes, Carbon atoms bond together to form a ring and there is no terminal Carbon. Due to formation of ring, every C atom must have to saturated with 2 Hydrogen atoms (see below example). So, for 'n' no. of C atoms there should be '2n' no. of H atoms. So, the formula is $C_{n}H_{2n}$ which is identical with the general formula for Alkenes.

Work Step by Step

a) Alkanes have the general formula $C_{n}H_{2n+2}$ whereas Alkenes have the general formula $C_{n}H_{2n}$. This is because in Alkenes there is double bond between two Carbon atoms i.e. all 'C' atoms are not completely saturated with H atoms (Carbons attached with double bond are bonded with 3 atoms. That's why the C is unsaturated) Where as in Alkanes all 'C' atoms are completely saturated with H atoms (Here, every C atoms are bonded with 4 atoms. That means complete saturation occur for every C atom) as there is only C-C single bond present in alkanes. b) See the answer with explanation.
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