Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 28 - Some Nonmetals and Metalloids - Exercises - Conceptual Exercises - Page 1083: 78

Answer

Elemental sulphur is much more stable and long-lasting there.

Work Step by Step

Elemental sulfur deposits are mined beneath the earth’s surface by the Frasch “hot water”. Elemental sulfur is only found on the earth’s surface near volcanoes and hot springs, where the water brings up H$_{2}$S which oxidizes to elemental sulfur by special anaerobic bacteria. In time, at the earth’s surface, the sulfur will continue to oxidize, with the help of aerobic bacteria, to thiosulfate $(S_{2}O _{3} ^{2-})$, tetrathionate $(S_4O_{6}^{2-} )$ and sulfate $(SO_4^{2-} )$ ions. The aerobic bacteria need oxygen to survive and therefore have far lower populations beneath the earth’s surface, so the elemental sulfur is much more stable and long-lasting there.
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