Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 12 - Thermodynamic Property Relations - Problems - Page 681: 12-38

Answer

$h_{2}-h_{1}=1869\text{ kJ/kg}$

Work Step by Step

Solving the equation of state for $v$ gives $$ v=\frac{R T}{P}+a $$ Then, $$ \left(\frac{\partial v}{\partial T}\right)_P=\frac{R}{P} $$ Using equation 12-35, $$ d h=c_P d T+\left[v-T\left(\frac{\partial v}{\partial T}\right)_P\right] d P $$ Substituting, $$ \begin{aligned} d h & =c_p d T+\left(\frac{R T}{P}+a-\frac{R T}{P}\right) d P \\ & =c_p d T+a d P \end{aligned} $$ Integrating this result between the two states gives $$ \begin{aligned} h_2-h_1 & =c_p\left(T_2-T_1\right)+a\left(P_2-P_1\right) \\ & =(5.1926 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K})(380-20) \mathrm{K}+\\&\left(0.01 \mathrm{~m}^3 / \mathrm{kg}\right)(750-150) \mathrm{kPa} \\ & =1875 \mathrm{~kJ} / \mathbf{k g} \end{aligned} $$ For an ideal gas, $$ d h=c_p d T $$ which when integrated gives $$ h_2-h_1=c_p\left(T_2-T_1\right)=(5.1926 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K})(380-20) \mathrm{K}=1869\ \mathbf{k J} / \mathbf{k g} $$
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