Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 12 - Thermodynamic Property Relations - Problems - Page 682: 12-63

Answer

This gas cannot be cooled by throttling since $\mu$ is always a negative quantity.

Work Step by Step

The equation of state of this gas can be expressed as $$ v=\frac{R T}{P}+a \longrightarrow\left(\frac{\partial v}{\partial T}\right)_P=\frac{R}{P} $$ Substituting into the Joule-Thomson coefficient relation, $$ \mu=-\frac{1}{c_p}\left(v-T\left(\frac{\partial v}{\partial T}\right)_P\right)=-\frac{1}{c_p}\left(v-T \frac{R}{P}\right)=-\frac{1}{c_p}(v-v+a)=-\frac{a}{c_p}<0 $$ Therefore, this gas cannot be cooled by throttling since $\mu$ is always a negative quantity.
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