Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 12 - Thermodynamic Property Relations - Problems - Page 684: 12-89

Answer

a) $c_{p}=1.045\text{ kJ/kg⋅K}$ b) $c_{p}=1.045\text{ kJ/kg⋅K}$

Work Step by Step

(a) We treat nitrogen as an ideal gas with $R=0.297 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K}$ and $k=1.397$. Note that $P T^{\mathrm{k}(k-1)}=C=$ constant for the isentropic processes of ideal gases. The $c_p$, relation is given as $$ \begin{aligned} c_p & =T\left(\frac{\partial P}{\partial T}\right)_x\left(\frac{\partial v}{\partial T}\right)_P \\ v & =\frac{R T}{P} \longrightarrow\left(\frac{\partial v}{\partial T}\right)_P=\frac{R}{P} \\ P & =C T^{k(k-1)} \longrightarrow\left(\frac{\partial P}{\partial T}\right)_x=\frac{k}{k-1} C T^{k(k-1)-1}=\frac{k}{k-1}\left(P T^{-k \cdot(k-1)}\right) T^{k(k-1)-1}=\frac{k P}{T(k-1)} \end{aligned} $$ Substituting, $$ c_p=T\left(\frac{k P}{T(k-1)}\right)\left(\frac{R}{P}\right)=\frac{k R}{k-1}=\frac{1.397(0.297 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K})}{1.397-1}=1.045 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K} $$ (b) The $c_p$ is defined as $c_p=\left(\frac{\partial h}{\partial T}\right)_p$. Replacing the differentials by differences, $$ c_p \equiv\left(\frac{\Delta h}{\Delta T}\right)_{P=300 \mathrm{P}_2}=\frac{h(410 \mathrm{~K})-h(390 \mathrm{~K})}{(410-390) \mathrm{K}}=\frac{(11,932-11,347) / 28.0 \mathrm{~kJ} / \mathrm{kg}}{(410-390) \mathrm{K}}=\mathbf{1. 0 4 5}\ \mathbf{k J} / \mathbf{k g} \cdot \mathbf{K} $$
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