Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 15 - Chemical Reactions - Problems - Page 795: 15-33

Answer

$AF_{}= 12.94\text{ kg air/kg fuel fuel}$

Work Step by Step

Analysis The balanced reaction equation for stoichiometric air is $$ \mathrm{CH}_3 \mathrm{OH}+a_{\text {th }}\left[\mathrm{O}_2+3.76 \mathrm{~N}_2\right] \longrightarrow \mathrm{CO}_2+2 \mathrm{H}_2 \mathrm{O}+a_{\text {th }} \times 3.76 \mathrm{~N}_2 $$ The stoicihiometric coefficient $a_{\mathrm{th}}$ is determined from an $\mathrm{O}_2$ balance: $$ 0.5+a_{\text {th }}=1+1 \longrightarrow a_{\text {th }}=1.5 $$ Substituting, $$ \mathrm{CH}_3 \mathrm{OH}+1.5\left[\mathrm{O}_2+3.76 \mathrm{~N}_2\right] \longrightarrow \mathrm{CO}_2+2 \mathrm{H}_2 \mathrm{O}+1.5 \times 3.76 \mathrm{~N}_2 $$ The reaction with $100 \%$ excess air and incomplete combustion can be written as $$ \mathrm{CH}_3 \mathrm{OH}+2 \times 1.5\left[\mathrm{O}_2+3.76 \mathrm{~N}_2\right] \longrightarrow 0.60 \mathrm{CO}_2+0.40 \mathrm{CO}+2 \mathrm{H}_2 \mathrm{O}+x \mathrm{O}_2+2 \times 1.5 \times 3.76 \mathrm{~N}_2 $$ The coefficient for $\mathrm{O}_2$ is determined from a mass balance, $\mathrm{O}_2$ balance: $$ 0.5+2 \times 1.5=0.6+0.2+1+x \longrightarrow x=1.7 $$ Substituting, $$ \mathrm{CH}_3 \mathrm{OH}+3\left[\mathrm{O}_2+3.76 \mathrm{~N}_2\right] \longrightarrow 0.6 \mathrm{CO}_2+0.4 \mathrm{CO}+2 \mathrm{H}_2 \mathrm{O}+1.7 \mathrm{O}_2+11.28 \mathrm{~N}_2 $$ The air-fuel mass ratio is $$ \mathrm{AF}=\frac{m_{\text {air }}}{m_{\text {fuel }}}=\frac{(3 \times 4.76 \times 29) \mathrm{kg}}{(1 \times 32) \mathrm{kg}}=\frac{414.1 \mathrm{~kg}}{32 \mathrm{~kg}}=12.94\ \mathrm{~kg} \text { air } / \mathrm{kg} \text { fuel } $$
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