Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 23 - Organic Chemistry I: Formulas, Names, and Properties - Exercises - Carboxylic Acids and Their Derivatives - Page 948: 77

Answer

a) Ethyl ethanoate b) Methyl ethanoate

Work Step by Step

a) First, find the functional group present in the molecule. Here, the functional group is $-COO-$. It means the compound is an ester. We divide the molecule into two part while naming ester. First part is alcohol part i.e. on the right side of -COO- group and the second is carboxylic acid part which is on the left side of -COO- group including -COO- group. Here, alcoholic part has 2 C in it ($CH_{2}CH_{3}$). So, the word root is 'eth' and we add suffix 'yl'. So, the alcoholic part has the name 'ethyl'. Carboxylic part has 2 C in it including -COO group. i.e. $CH_{3}COO$ part. So, the word root is 'eth' and ending name is 'anoate' for ester group. So, we write the alcoholic part and after a space write the carboxylic acid part for naming ester. Here, it is 'ethyl ethanoate'. b) a) First, find the functional group present in the molecule. Here, the functional group is $-COO-$. It means the compound is an ester. We divide the molecule into two part while naming ester. First part is alcohol part i.e. on the right side of -COO- group and the second is carboxylic acid part which is on the left side of -COO- group including -COO- group. Here, alcoholic part has 1 C in it ($CH_{3}$). So, the word root is 'meth' and we add suffix 'yl'. So, the alcoholic part has the name 'methyl'. Carboxylic part has 2 C in it including -COO group. i.e. $CH_{3}COO$ part. So, the word root is 'eth' and ending name is 'anoate' for ester group. So, we write the alcoholic part and after a space write the carboxylic acid part for naming ester. Here, it is 'methyl ethanoate'.
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