Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 28 - Some Nonmetals and Metalloids - Exercises - The Noble Gases - Page 1080: 6

Answer

The accidental preparation of O$_2 $ $^+PtF6^-$ by the reaction of O$_2$ with PtF$_6$ led Bartlett to reason that xenon should also be oxidized by PtF$_6$, since the first ionization energy of molecular oxygen is actually slightly larger than that of xenon. He obtained a red crystalline solid initially believed to be $Xe^+PtF_6^{-}$, but now known to be more complex. At present, Xe and Kr are the only noble gases known to form compounds, mostly combining with F and O. Our textbook discusses the compounds of Xe.

Work Step by Step

The accidental preparation of O$_2 $ $^+PtF6^-$ by the reaction of O$_2$ with PtF$_6$ led Bartlett to reason that xenon should also be oxidized by PtF$_6$, since the first ionization energy of molecular oxygen is actually slightly larger than that of xenon. He obtained a red crystalline solid initially believed to be $Xe^+PtF_6^{-}$, but now known to be more complex. At present, Xe and Kr are the only noble gases known to form compounds, mostly combining with F and O. Our textbook discusses the compounds of Xe.
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