Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 3 - Mass Relationships in Chemical Reactions - Questions & Problems - Page 111: 3.93

Answer

Theoretical yield: 20.6 g Percent yield: 29.0 %

Work Step by Step

- Calculate or find the molar mass for $ Li $: $ Li $ : 6.941 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 12.3 \space g \times \frac{1 \space mole}{ 6.941 \space g} = 1.77 \space moles$$ - Calculate or find the molar mass for $ N_2 $: $ N_2 $ : ( 14.01 $\times$ 2 )= 28.02 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 33.6 \space g \times \frac{1 \space mole}{ 28.02 \space g} = 1.20 \space moles$$ Find the amount of product if each reactant is completely consumed. $$ 1.77 \space moles \space Li \times \frac{ 2 \space moles \ Li_3N }{ 6 \space moles \space Li } = 0.590 \space mole \space Li_3N $$ $$ 1.20 \space moles \space N_2 \times \frac{ 2 \space moles \ Li_3N }{ 1 \space mole \space N_2 } = 2.40 \space moles \space Li_3N $$ Since the reaction of $ Li $ produces less $ Li_3N $ for these quantities, it is the limiting reactant. - Calculate or find the molar mass for $ Li_3N $: $ Li_3N $ : ( 6.941 $\times$ 3 )+ ( 14.01 $\times$ 1 )= 34.83 g/mol - Using the molar mass as a conversion factor, find the mass in g: $$ 0.590 \space mole \times \frac{ 34.83 \space g}{1 \space mole} = 20.6 \space g$$ - Calculate the percent yield $$percent \space yield = \frac{5.89 \space g}{20.6 \space g} \times 100\% = 29.0 \%$$
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