Answer
Yes, the ship traveling at 25 knots is faster than my car traveling at $25\,\mathrm{mi/h}$.
Work Step by Step
Conversion factor: 1 nautical mile = 1.151 mile
A ship traveling at 25 nautical miles per hour, has a speed of $28.77\,\mathrm{mi/h}$.
This is greater than the $25\,\mathrm{mi/h}$ my car travels in. Thus, the ship is moving faster.