Answer
a). $12.5s$
b). $56.25m$ from starting point of runner with speed 4.5 m/s.
Work Step by Step
Their relative velocity or the velocity of approach = $4.5+3.5=8 m/s$
Initial distance = 100m.
So, time taken to cover this distance is $=\frac{100}{8}=12.5 s$
In 12.5 s, the runner with speed 4.5 m/s would cover $=4.5\times 12.5 = 56.25m$