Thermodynamics: An Engineering Approach 8th Edition

Published by McGraw-Hill Education
ISBN 10: 0-07339-817-9
ISBN 13: 978-0-07339-817-4

Chapter 16 - Chemical and Phase Equilibrium - Problems - Page 833: 16-62C

Answer

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Work Step by Step

The molar concentration $C_{\mathrm{i}}$ of the gas species $i$ in the solid at the interface $C_{\mathrm{i} \text {, solid side }}(0)$ is proportional to the partial pressure of the species $i$ in the gas $P_{\mathrm{i} \text {, gas side }}(0)$ on the gas side of the interface, and is determined from $$ C_{\mathrm{i}, \text { solidside }}(0)=\mathrm{S} \times P_{\mathrm{i}, \text { gasside }}(0) \quad\left(\mathrm{kmol} / \mathrm{m}^3\right) $$ where $\mathrm{S}$ is the solubility of the gas in that solid at the specified temperature.
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