Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 3 - Chemical Equations and Reaction of Stoichiometry - Exercises - Percent Yield from Chemical Reactions - Page 109: 42

Answer

(a)Theoretical yield of $O_2$=2.26g (b)Percent yeild=46.46%

Work Step by Step

$KClO_3$ molar mass=122.55amu $O_2$ molar mass=32amu (a)We calculate the number of moles of $KClO_3$ using the formula: Number of moles=$\frac{\text{mass}}{\text{molecular mass}}=\frac{5.79}{122.55}\approx0.047mol$ We write a balanced chemical reaction for the decomposition of $KClO_3$ to potassium chloride and water: $2KClO_3\rightarrow 2KCl+3O_2$ According to the balanced chemical reaction, 2moles of $KClO_3$ will produce 3 moles of $O_2$. So, 0.047mol $KClO_3$ will produce: $0.047mol $KClO_3$\times\frac{3mol(O_2)}{2mol($KClO_3$)}=0.0705mol$ We can then calculate the mass of oxygen using the formula: mass of oxygen=number of moles of oxygen$\times$molar mass of oxygen($O_2$)=$0.0705\times32\approx2.26g$ Theoretical yield of oxygen gas=2.26g (b)Percent yeild=$\frac{\text{Actual yeild}}{\text{theoritical yeild}}\times100=\frac{1.05}{2.26}\times100\approx46.46\%$
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