Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition)

Published by Prentice Hall
ISBN 10: 0321908449
ISBN 13: 978-0-32190-844-5

Chapter 10 - Section 10.7 - Buffers - Additional Questions and Problems - Page 357: 10.79c

Answer

Solution A: $[OH^-] = 1\times 10^{-10}M$ Solution B: $[OH^-] = 1 \times 10^{-8}M$

Work Step by Step

As we have calculated on 10.79b: Solution A: $[H_3O^+] = 1 \times 10^{- 4}M$ Solution B: $[H_3O^+] = 1 \times 10^{-6}M$ For the first solution (A): 1. Write the $K_w$ expression for the water equilibrium. Then substitute the value for $[H_3O^+]$, and solve for $[OH^-]$: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $1 \times 10^{-4} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{1 \times 10^{-4}}$ $[OH^-] = 1\times 10^{-10}M$ ---------- For the second solution (B): 2. Write the $K_w$ expression for the water equilibrium. Then substitute the value for $[H_3O^+]$, and solve for $[OH^-]$: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $1 \times 10^{-8} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{1 \times 10^{-8}}$ $[OH^-] = 1 \times 10^{-8}M$
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