Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition)

Published by Prentice Hall
ISBN 10: 0321908449
ISBN 13: 978-0-32190-844-5

Chapter 10 - Section 10.7 - Buffers - Additional Questions and Problems - Page 357: 10.80c

Answer

Solution $X$: $[OH−]=1×10^{-5}M$ Solution $Y$: $[OH−]=1×10^{-7}M$

Work Step by Step

As we have calculated on 10.79b: Solution X: $[H_3O^+]=1×10^{−9}M$ Solution Y: $[H_3O^+]=1×10^{−7}M$ For the first solution (X): 1. Write the Kw expression for the water equilibrium. Then substitute the value for $[H_3O^+]$, and solve for $[OH^−]$: $[H_3O^+][OH^−]=K_w=10^{−14}$ $1×10^{−9}\times[OH−]=10^{−14}$ $[OH−]=\frac{10^{−14}}{1×10^{−9}}$ $[OH−]=1×10^{-5}M$ For the second solution (Y): 2. Write the Kw expression for the water equilibrium. Then substitute the value for $[H_3O^+]$, and solve for $[OH^−]$: $[H_3O^+][OH^−]=K_w=10^{−14}$ $1×10^{−7}\times[OH−]=10^{−14}$ $[OH−]=\frac{10^{−14}}{1×10^{−7}}$ $[OH−]=1×10^{-7}M$
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