Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Chapter 3 - Topic 3A - Entropy - Exercises - Page 149: 3A.6(b)

Answer

30.1 kJ/mol

Work Step by Step

Recall that $\Delta S_{vap}=\frac{\Delta H_{vap}}{T_{b}}$. $\implies \Delta H_{vap}=\Delta S_{vap}\times T_{b}$ Given that $T_{b}=80.7^{\circ}C=(80.7+273.15)K=353.85\,K$ For cyclohexane, $\Delta S_{vap}=85.1\,J\,K^{-1}mol^{-1}$ Then, $\Delta H_{vap}=(85.1\,J\,K^{-1}mol^{-1})(353.85\,K)$ $=30100\,J\,mol^{-1}=30.1\,kJ/mol$
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