Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Chapter 3 - Topic 3A - Entropy - Exercises - Page 149: 3A.7(a)

Answer

$152.67\,JK^{-1}mol^{-1}$

Work Step by Step

Entropy variation with the temperature at constant-volume is given by the equation $S(T_{f})=S(T_{i})+C_{v}\ln\frac{T_{f}}{T_{i}}$ From table 2C.5, we have, for neon gas, $C_{p}=20.786\,J\,K^{-1}mol^{-1}$ $C_{v}=C_{p}-R=(20.786-8.314)\,J\,K^{-1}mol^{-1}$ $=12.472\,J\,K^{-1}mol^{-1}$ $S(T_{i})=S(298\,K)=146.22\,J\,K^{-1}mol^{-1}$ Then, $S(T_{f})=S(500\,K)$ $=(146.22\,J\,K^{-1}mol^{-1})+(12.472\,J\,K^{-1}mol^{-1})\ln\frac{500}{298}$ $=152.67\,JK^{-1}mol^{-1}$
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